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Buku Alkaline-Earth Metal Compounds by Sjoerd Harder

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Alkaline-Earth Metal Compounds by Sjoerd Harder

Author:Sjoerd Harder

Language: eng

Format: epub

Publisher: Springer Berlin Heidelberg, Berlin, Heidelberg

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Alkaline-Earth Metal Compounds by Sjoerd Harder

Mulvey, Hevia and co-workers found a similar reactivity (i.e. reactivity via all of its butyl anions) in their C-metallation of 1-methylindole with the higher order sodium magnesiate Na2MgBu4·2TMEDA crystallographically characterising the product of a 4:1 stoichiometric reaction as the Weiss motif Na2Mg(indol-2-yl)4·2TMEDA [86].

Similarly, Hoarau and Marsais successfully applied the lower order ate LiMgBu3 for the regioselective ortho-deprotonation of (4′,4′-dimethyloxazolin-2-yl)benzene, with the reaction proceeding at synthetically desirable room temperature in THF [87].

 

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Alkaline-Earth Metal Compounds by Sjoerd Harder

Author:Sjoerd Harder , Date: September 29, 2019

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Author:Sjoerd Harder

Language: eng

Format: epub

Publisher: Springer Berlin Heidelberg, Berlin, Heidelberg
Mulvey, Hevia and co-workers found a similar reactivity (i.e. reactivity via all of its butyl anions) in their C-metallation of 1-methylindole with the higher order sodium magnesiate Na2MgBu4·2TMEDA crystallographically characterising the product of a 4:1 stoichiometric reaction as the Weiss motif Na2Mg(indol-2-yl)4·2TMEDA [86].

Similarly, Hoarau and Marsais successfully applied the lower order ate LiMgBu3 for the regioselective ortho-deprotonation of (4′,4′-dimethyloxazolin-2-yl)benzene, with the reaction proceeding at synthetically desirable room temperature in THF [87].

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